GUJARAT TECHNOLOGICAL UNIVERSITY
BE- SEMESTER-V (NEW) EXAMINATION — WINTER 2020
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Subject Code:3152601 Date:27/01/2021
Subject Name:Vulcanization
Time:10:30 AM TO 12:30 PM Total Marks: 56
Instructions:
- Attempt any FOUR questions out of EIGHT questions.
- Make suitable assumptions wherever necessary.
- Figures to the right indicate full marks.
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MARKS
- (a) Why selenium is not used as a vulcanizing agent though it takes same place along with sulphur in periodic table? 03
- (b) Distinguish vulcanized rubber and unvulcanized rubber 04
- (c) Explain the construction and working of Oscillating Disc Rheometer(ODR) with labeled diagram. 07
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- (a) List the major components of structure of rubber vulcanizate. 03
- (b) Construct the labeled diagram showing different types of crosslinks are formed during the sulphur vulcanization 04
- (c) Explain the vulcanization of thick rubber article. 07
- (a) List any two examples of sulphur donors with their structure. 03
- (b) Illustrate sulphur vulcanization crosslinking network structure with suitable diagram. 04
- (c) Write a short note on Sulphenamide accelerator. 07
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- (a) List out any two examples of peroxides with carboxyl group with their structure. 03
- (b) Illustrate post vulcanization reaction network reaction with suitable diagram. 04
- (c) Write a short note on Dithiocarbamate accelerator. 07
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- (a) List out the different phases observed during free heating. 03
- (b) Compare the saturated steam vulcanization and superheated steam vulcanization. 04
- (c) Explain the chemical method and physical method respectively to assess the state of cure. 07
- (a) How vulcanization is carried out in jacketed autoclave? 03
- (b) Compare different continuous vulcanization line on the basis of their key features. 04
- (c) Explain the limitations of vulcanization temperature. 07
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- (a) Summarize the principle of electone beam vulcanization technique. 03
- (b) How vulcanization is carried out through rotocure? 04
- (c) Explain the vulcanization in water. 07
- (a) Summarize the principle of microwave curing. 03
- (b) What are advantages and disadvantages of Liquid Curing Method (LCM)? 04
- (c) Explain the fluid bed vulcanization. 07
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