This download link is referred from the post: SGBAU B.Tech Last 10 Years 2010-2020 Question Papers || Sant Gadge Baba Amravati university
Pages: 3
Time : Three Hours
10994 : Applied Physical Chemistry : 4 CH 04
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AW - 3067
Max. Marks : 80
Notes :
Answer three questions from Section A and three questions from Section B.
Assume suitable data wherever necessary.
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Diagrams and chemical equations should be given wherever necessary.
Illustrate your answer necessary with the help of neat sketches.
Discuss the reaction, mechanism wherever necessary.
Use of pen Blue/Black ink/refill only for writing the answer book.
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- What is conductance of an electrolyte? Explain different types of conductometric titrations. (6)
- How will you determine pH of unknown solution for following cell, using EMF measurement? (4)
Hg | Hg2Cl2(KClSat) || unknown. c, pH | Pt - The molar conductance at infinite dilutions for sodium acetate and hydrogen chloride at 30°C are 91.0x10-5 and 426.16x10-5 Sm2mol-1 respectively. Also for H+ ions in HCl, t+ is 0.821 and for CH3COO- ions in CH3COONa, t- is 0.556. Assuming that t+ = t-. Calculate Λ°m for CH3COOH. (4)
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OR
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- What are concentration cells? Derive expressions for the EMF of concentration cells. (6)
- With transference
- Without transference
- What do you mean by specific and equivalent conductance of an electrolytic solutions? Write their interrelation. (4)
- At 25°C, the degree of dissociation (α) of pure water is 1.90x10-7. Calculate the molar conductance (Λ°m) and specific conductance (k) of water at this temperature. The molar ionic conductance of H+ and OH- ions are 349.83x10-5 and 198.50x10-5 Sm2 mol-1 respectively. (4)
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- What are concentration cells? Derive expressions for the EMF of concentration cells. (6)
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- Define collision parameter and derive an expression for collision number. (6)
- State law of corresponding state. (3)
- Critical constants for benzene are Tc =560.5k and Pc =47.5atm . Calculate the van-der wall's constants. (4)
OR
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- Deduce the Virial equation of state from Vander wall's equation and critical state. (6)
- State the postulates of Kinetic theory of gases. (3)
- Find average and most probable velocity of CO2 gas at 30°C. (R =8.314 J K-1mol-1) (4)
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- State Stark - Einstein law of photochemistry and give the examples of photochemical reactions which shows deviation from this law. (6)
- Define: (3)
- Wavelength
- Wave number
- Chemical shift
- What is the selection rule for IR and NMR spectroscopy? (4)
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OR
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- Derive an expression for moment of Inertia frequency of spectral lines of a diatomic molecule acts as rigid rotator. (6)
- Define: (3)
- Electromagnetic spectrum
- Photosensitization
- Phosphorescence
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- Define Quantum yield of photochemical reaction. Give the reason of low quantum yield of a photochemical reaction. (4)
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- State and explain BET equation for multilayer adsorption. (6)
- Distinguish between physisorption and chemisorption. (3)
- Explain homogenous catalysis with acid - base catalysis. (4)
OR
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- Derive Langmuir adsorption isotherm. Write the factors on which adsorption depends. (6)
- Explain the various characteristics of catalyst. (3)
- Explain the following with examples. (4)
- Catalytic poisoning
- Auto catalysis
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- Derive rate equation for first order reaction and write two examples (reactions). (6)
- In first order reaction, it takes the reactant 40.5 min. to be 25% decomposed. Calculate the rate constant of reaction. (3)
- What is Zero order reaction. Explain with example. (4)
OR
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- Show that for first order reaction, the time required for 99.9% completion of the reaction is 10 times that required for 50% completion. (3)
- What is order of reaction? Explain Pseudo - unimolecular reaction with example. (4)
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- Discuss the thermodynamic scale of temperature. (6)
- State first law of thermodynamics with its limitations. (4)
- Define (4)
- Enthalpy
- Entropy
- Gibb's free energy
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OR
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- State the third law of thermodynamics and Explain how absolute entropy can be calculated from this law. (6)
- Define (4)
- Free Energy
- Chemical potential
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- Explain the following (3)
- Isolated system
- Open system
- Adiabatic process
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This download link is referred from the post: SGBAU B.Tech Last 10 Years 2010-2020 Question Papers || Sant Gadge Baba Amravati university