All questions carry equal marks
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1.a) Write the methods of preparations of cycloalkanes.
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b) Describe Bayer?s Strain Theory and Orbital pictures of angle strain. [7+7]2.a) Explain about different types of reactions.
b) Describe about SN1 Vs SN2 solvolyses and what is the role of solvents in SN1 reactions.
[7+7]
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3.a) What is Walden inversion and What is peroxide effect?
b) Describe cyclo addition reactions with suitable examples. [8+6]
4.a) Explain the following:
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i) Hyper conjugationii) Mesomeric effect.
b) How do you convert the following:
i) Benzene to Toluene
ii) Benzene to Acetophenone. [6+8]
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5.a) Explain reactivity and orientation, activating and deactivating, O, M, P directing groups
in electrophillic aromatic substitution.
b) Write the methods of synthesis and chemical reactions of carboxylic acids. [7+7]
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6. Explain the following named reactions:a) Aldol Condensation
b) Witting reaction
c) Reimer tiemann?s reaction
d) Williamson synthesis. [14]
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7.a) How do you prepare diazonium salt? Write its chemical properties.
b) Explain basicity of amines. [7+7]
8. Explain the methods of preparation, test for purity, assay and medicinal uses of
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a) Aspirinb) Benzylbezoate
c) Citric acid
d) Dimercaprol [14]
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