Subject Title: Chemistry II Prepared by: K Sunitha
Year: 1st Semester: II Updated on:11-02-2020
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Unit - I: Inorganic Chemistry
- What are oxides? How are they classified? Explain the structures of oxides of Carbon & phosphorous.
- What are inter halogens? Explain the structure of ICl2, IF5, IF7.
- What are poly halides? Give a note of structures of ICl2-, ICl4- and I3-
- What are pseudo halogens? How are they differed from halogens.
- What are clathrate compounds? Give examples.
- Give a note on Halides of Xe.
- Explain the structure of XeO3 & XeO4.
- Explain the structure of Oxyacids of Xe.
- Give Electronic configurations of
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a. Ruthenium b. Silver c. Platinum d. Gold - Explain the magnetic properties of Transition elements?
- Explain the stability of various oxidation states in transition elements?
- How 2nd and 3rd transition series differs with 3d series
- Give a note on Cr & Cu triads?
- Give a note on Ti triads?
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UNIT-II. Organic chemistry
- Explain SN1 mechanism and its stereochemistry?
- Give a note on energy profile diagram of SN1 & SN2 respectively?
- Explain SN2 reaction mechanism with stereochemistry?
- Give a note on Recemisation and walden inversion?
- Give a note on ease of hydrolysis of Alkyl halides?
- How RMgX is formed from Alkyl halides? Give an examples
- How 1°,2° and 3°alkyl halides are prepared?
- Explain the acidic nature of phenols?
- Give a mechanism of oppenauer oxidation?
- Explain following reaction mechanism
a. Reimer-Tiemer reaction b. Kolbe electrolysis mechanism - Give a note on Electrophilic reaction mechanism in phenols
- Give a note on following
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a. Azo-coupling b. Gattermann-koch mechanism - Give a note on willimson’s synthesis?
- How alcohols are prepared from Grignard reagent
- How phenols are prepared from diazonium salts and cumene hydroperoxides?
- How carbonyl compounds are prepared from
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A. Acid chlorides B. 1,3- dithials - Give chemical reactions of
A. Cannizaro reaction B. Hemi acetal and C. acetal formation - Give chemical reactions for reduction of carbonyl compounds, carboxylic acides and esters?
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UNIT - 3: (physical chemistry) Electrochemistry
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- Define the following
a. Specific conductance b. Equivalent conductance - What is Migration of ions?
- State and explain Kholraussch’s law
- Explain Arhenius theory of electrolysis dissociation
- State and explain Ostwald’s dilution law?
- Explain debye-Huckel onsagar’s equation for strong electrolytes?
- What is Transport number? How it is determined by Hittorf's method?
- Give a note on degree if dissociation
- Explain the construction of Galvanic cell
- Explain the construction of Gas electrodes?
- Explain the construction of standard hydrogen electrode?
- What are potentiometric titrations?
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UNIT-4 (General chemistry)
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- What are indicators? How are they selected?
- What are titrations? Explain the types?
- Explain the theories of indicators?
- What are complexometric titrations? Give the structure of EBT, fast sulphon black & murexide indicators?
- Explain the role of pH in complexeometric titrations?
- How Ni++ is determined by gravimetry?
- Define a. wave length
b. Plane of polarized light
c. Optical rotation d. Specific rotation - Explain centre and Sn axis of symmetry with examples
- D,L configuration with examples
- R, S configurations with examples?
- What are colligative properties
- State and explain Raoult’s law?
- What is osmotic pressure? How it is determined?
- What is Elevation in boiling point? How molecular weight can be calculated?
- What is depression in freezing point
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