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Code No. 3300/E
FACULTY OF SCIENCE
B.Sc. VI-Semester (CBCS) Examination, May / June 2019
Subject : Chemistry
Paper - VII (DSC)
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Time : 3 Hours Max. Marks: 60
PART - A (5 x 3 = 15 Marks)
(Short Answer Type)
Note : Answer any FIVE of the following questions.
- Define Labile and Inert complexes. Give one example each.
- Write the biological significance of Na and Mg.
- Give Lobry de bruyn Van Ekenstein rearrangement.
- What is meant by Isoelectric point? Give suitable example.
- Derive Cp— Cv=R.
- Write about various state functions and path functions.
- What are equivalent and nonequivalent protons?
- Write about the entropy change for spontaneous, Non spontaneous and equilibrium processes.
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PART — B (45 Marks)
(Essay Answer Type)
Note: Answer ALL from the questions.
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(a) Explain SN1 reactions of octahedral complexes.
OR
(b) Explain Pearson’s classification of Hard and Soft Acids and Bases.
-
(a) Explain the following:
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- Mutarotation
- Anomers
- Epimers
OR
(b) How are Alanine and Valine prepared from Malonic ester synthesis?
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-
(a) Explain Carnot cycle. Derive an expression for the efficiency of reversible heat engine working between T2 and T1 temperatures.
OR
(b) State and explain I law of thermodynamics.
-
(a) Explain the basic principles of mass spectroscopy.
OR
(b) Derive Gibbs-Helmholtz equation.
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