GUJARAT TECHNOLOGICAL UNIVERSITY
BE - SEMESTER- IV (New) EXAMINATION - WINTER 2019
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Subject Code: 2141306 Date: 07/12/2019
Subject Name: Elements of Chemical Engg
Time: 02:30 PM TO 05:00 PM Total Marks: 70
Instructions:
- Attempt all questions.
- Make suitable assumptions wherever necessary.
- Figures to the right indicate full marks.
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MARKS
Q.1
- (a) Differentiate between elementary and non-elementary reaction. 03
- (b) Explain Single and multiple reactions with one example. 04
- (c) Define (i) Rate constant (ii) PFR (iii) Molecularity (iv) Order of reaction (v) Collision (vi) Activation energy (vii) Rate of reaction 07
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Q.2
- (a) Differentiate between (i) Homogeneous Reaction (ii) Heterogeneous Reaction. 03
- (b) Define rate of reaction and give the relation between rate of reaction and temperature. 04
- (c) Explain Temperature dependency from Arrhenius’s law. 07
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OR
- (c) Explain Temperature dependency from collision theory. 07
Q.3
- (a) What are the ways to control product distribution in parallel reaction? 03
- (b) Draw a neat sketch with application of (i) Semi batch reactor (ii) Mix flow reactor. 04
- (c) At 27°C, a reaction has a rate constant of 0.010 s-1. At what temp, would the reaction be twice as fast? E= 50 KJ/mol. (Assume, Concentration of reactant and E is unchanged.) 07
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OR
- (a) Write a Short note on batch reactor. 03
- (b) Write about the advantages and disadvantages of continuous reactor. 04
- (c) Milk is pasteurized if it is heated to 63°C for 30 min, but if it is heated to 74°C it only needs 15 s for the same result. Find the activation energy of this sterilization process. 07
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Q.4
- (a) Enlist the classification of reactions. 03
- (b) Explain the second order reaction with example. 04
- (c) Derive a performance Equation for CSTR. 07
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OR
- (a) Write down only the temperature dependency equation from collision theory for like and unlike molecules. 03
- (b) Explain experimental methods for F - curve. 04
- (c) Derive a material balance Equation for ideal batch reactor. 07
Q.5
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- (a) Enlist & explain the ways to transfer heat. 03
- (b) Explain experimental methods for E - Curve. 04
- (c) List out the methods of R measurement. 07
OR
- (a) Give the difference between ideal flow and non-ideal flow. 03
- (b) State and explain thermodynamics law with example. 04
- (c) Explain the procedure to convert I curve to E curve obtained from step Input. 07
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