GUJARAT TECHNOLOGICAL UNIVERSITY
BE - SEMESTER-III (NEW) EXAMINATION - SUMMER 2019
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Subject Code: 2132301
Subject Name: Introduction to Plastic Material Science
Time: 02:30 PM TO 05:00 PM
Instructions:
- Attempt all questions.
- Make suitable assumptions wherever necessary.
- Figures to the right indicate full marks.
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Q1
- Define: Monomer, Homochain Polymer, Initiator [03]
- Give functionality of: (i) HOOCCH2COOH (ii) C6H5CH2OH (iii) CH2CH(OH)COOH (iv) H2NCH2(CH2)5CH2NH2 [04]
- Give classification of Polymers giving suitable examples. [07]
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Q2
- Describe Bulk polymerization technique with advantages. [03]
- Give structures of: PVC, PAN, PMMA, PP [04]
- Differentiate between low molecular weight compound and polymers. [07]
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OR
- Explain various steps of Cationic Polymerization. [07]
Q3
- Discuss: Linear, Branched and crosslinked polymer structures. [03]
- Give difference between Step and Chain polymerization. [04]
- You have a polymer sample that contains the following molecules: [07]
Mi, g/mol N
1,000,000 2
700,000 5
400,000 10--- Content provided by FirstRanker.com ---
100,000 4
50,000 2
Total 23
What are Mn, Mw and the polydispersity index?
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OR
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- Calculate the contour length and the extended chain length of PE Mol. [07]
Given: - n =5000., Bond angle-109°28', Segment length -1.54 Å.
Q4
- Write a note on: Suspension Polymerization. [03]
- List the types of Chain Polymerization? Explain Free radical Polymerization in detail. [04]
- Calculate the degree of polymerization of a sample of polyethylene [(CH2-CH2)n], which has a molecular weight of 150,000 g/mol. [07]
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OR
- What are inhibitors? Give its types and its uses. [03]
- Explain effect of crystallinity on the properties of Polymer. [04]
- Discuss about the tacticity of polymers with example. [07]
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Q5
- What do you mean by Homopolymer and Copolymer? List the types of copolymers and explain them with suitable example. [03]
- Explain factors influencing the Glass transition temperature with suitable examples. [04]
- Plot graph for specific volume v/s temperature for highly crystalline, amorphous and partially crystalline polymers and explain. [07]
OR
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- Explain Polydispersity & Molecular weight distribution in polymers. [03]
- Explain relation between: Tg & Molecular weight [04]
- Explain Emulsion Polymerization technique with schematic diagram. [07]
Date: 04/06/2019
Total Marks: 70
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