2.SeparationoftwocomponentmixturebyTLCandcalculationofRfvalueforeachcoponent.
SubmissionoftheTLCplatewithbetterseparationoftwocomponentsofthemixture.05Btlurks
3.VivaandRecord0SMarks
______._.
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Totalt25Marks?_.__?__._.
)4?)
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SCHEME0FVALUATIONB.Sc.lllYear,Semester-VPracticalExamination
SubjectzChemislry
Paper-V(OrganicSynthesisandTLC)(CHE551)
1a)Principle,reactionandmechanismforthepreparationoftliegivenorganiccompound03Marks
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b]Preparationandsubmissionofthecrudcsampleofanorganiccompound12Marks2.SeparationoftwocomponentmixturebyTLCandcalculationofRfvalueforeachcoponent.
SubmissionoftheTLCplatewithbetterseparationoftwocomponentsofthemixture.05Btlurks
3.VivaandRecord0SMarks
______._.
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Totalt25Marks?_.__?__._.
)4?)
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FACULTYOF
SCIENCE
B.Sc.lllYear,Semester-VPracticalExainations,2018
Subject:Chemistry
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Paper-V(OrganicSynthesisandTLC)(CHES51)QuestionBank
Time:2HoursMax.Marksz25
Ia)Writetheprinciple,reactionandmechanismforthepreparationofanorganiccompound
fromthelistgivenbelow:(03Marks)
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1.Aspirin7.Benzoicacid2.Bcnznnilide8.N-Butylacetate
3.Nitrobenzene9.B-Naphthylmethylether
4.m-Dinitrobenzene10.Benzyliclencaniline
S.p-Bromoacetanilide_l1.PhenylamIS-naphthol
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:6.2,4,6-'l'ribro|nophenolb)Prepareanclsubmitthecrudesampleofanorganiccompoundfromthelistgivenbelow:
(IIMarks)
l.Aspirin7.Benzoicacid
2.
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Benzauilide8.
N-Butylacetate
3.Nitrobenzene9.B-Naphthylmethylether
4.m-Diniuobcnzenel0.Benzylideneaniline
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S.p-Bromoaeetanilide11.Phenylaz/aB-nziphthol6.2,4,6@Tribromophenol
H.SeparatethetwocomponentmixturebyTLCandcalculatetheR;valeforeachcomponent.
SubmittheTLCplatewithbetterseparationoftwocomponentsofthemixture.(05Marks)
l.2,4-DinirrophenylhydrazoncsofacetoneandZ-butanonemixture
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2.onho-andpnru-NitroanilinemixturellI.VivaandRecord~
~((l5Marks)
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