B.PHARM. DEGREE EXAMINATION
SECOND YEAR
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PAPER II - PHARMACEUTICAL ANALYSIS & PHYSICAL CHEMISTRY
Time: Three hours Maximum: 100 Marks
Answer All Questions
SECTION-A
(PHARMACEUTICAL ANALYSIS)
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I. Elaborate on: (1x20=20)
- a) What is Non-Aqueous Titration? Write the types of solvents used in Non-Aqueous Titration with examples?
b) Explain in detail about neutralization curve in acid base titration.
II. Write notes on: (4x5=20)
- What is argentimetric titration? Explain briefly Mohr’s method.
- Write the preparation and standardization of potassium permanganate.
- Explain the theories of acid-base indicators.
- Give the principle and procedure behind Kjeldahl method of nitrogen estimation.
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III. Short answers on: (5x2=10)
- Define buffer capacity.
- Define acid value. What is its importance?
- What are chelating agents?
- What is co-precipitation and post precipitation?
- What is solubility product?
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SECTION-B
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(PHYSICAL CHEMISTRY)
I. Elaborate on: (1x20=20)
- Define rate of reaction. Give a detailed account of the theories of reaction rates.
II. Write notes on: (4x5=20)
- State and explain Joule-Thomson effect.
- Define enthalpy of combustion. With a neat labeled diagram explain the working of bomb calorimeter.
- Write short notes on adsorption isotherms.
- Explain the principle and working of refractometer.
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III. Short answers on: (5x2=10)
- Define phase transfer catalyst and give examples.
- What is ideal solution? Write any two characteristics of an ideal solution.
- Lavoisier- Laplace law.
- Define molar heat capacity and give its unit.
- What is plane polarized light?
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