[BPHARM 0122] JANUARY 2022 Sub. Code: 4257
(AUGUST 2021 EXAM SESSION)
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B.PHARMACY DEGREE COURSE (NON-SEMESTER EXAMINATIONS)
SECOND YEAR (Regulation 2009-2010)
PAPER II - PHARMACEUTICAL ANALYSIS & PHYSICAL CHEMISTRY
Q.P. Code: 564257
Time: Three hours Answer ALL questions Maximum: 100 Marks
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SECTION-A
(PHARMACEUTICAL ANALYSIS)
I. Elaborate on: (1x20=20)
- a) Explain briefly about various steps involved in gravimetric analysis by illustrating the determination of Magnesium as magnesium pyrophosphate.
- b) Discuss about various methods of end point detection in Complexometric titrations.
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II. Write notes on: (4x5=20)
- Discuss briefly on Henderson-Hasselbalch equation.
- Brief out on the types of Errors.
- Illustrate the preparation and standardization of tetrabutyl ammonium hydroxide.
- Write a note on redox indicators.
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III. Short answers on: (5x2=10)
- Accuracy & Precision.
- Leveling effect.
- Diazotization titration.
- Acid value & lodine value.
- Mercurimetric titration.
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SECTION-B
(PHYSICAL CHEMISTRY)
I. Elaborate on: (1x20=20)
- a) Define order of reaction. Explain various methods for determining the order of reaction.
- b) Elaborate briefly on the Principle, Instrumentation and Applications of polarimeter.
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II. Write notes on: (4x5=20)
- Define solution. Write a note on the types of Solution.
- Describe the working of a Carnot cycle.
- Explain Hess’s law of constant heat of summation.
- Write a note on phase transfer catalysts.
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III. Short answers on: (5x2=10)
- Ideal and real solutions.
- Enthalpy of combustion.
- Types of adsorption isotherms.
- Enzyme catalysts
- Concept of activation energy.
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