Search results for: “aster”

PHYSICAL CHEMISTRY

Structure: Quantum theory: principles and techniques; applications to a particle in a box, harmonic oscillator, rigid rotor and hydrogen atom; valence bond and molecular orbital theories, Huckel approximation; approximate techniques: variation and perturbation; symmetry, point groups; rotational, vibrational, electronic, NMR, and ESR spectroscopy

Equilibrium: Kinetic theory of gases; First law of thermodynamics, heat, energy, and work; second law of thermodynamics and entropy; third law and absolute entropy; free energy; partial molar quantities; ideal and non-ideal solutions; phase transformation: phase rule and phase diagrams ? one, two, and three component systems; activity, activity coefficient, fugacity, and fugacity coefficient; chemical equilibrium, response of chemical equilibrium to temperature and pressure; colligative properties; Debye-Huckel theory; thermodynamics of electrochemical cells; standard electrode potentials: applications ? corrosion and energy conversion; molecular partition function (translational, rotational, vibrational, and electronic).

Kinetics: Rates of chemical reactions, temperature dependence of chemical reactions; elementary, consecutive, and parallel reactions; steady state approximation; theories of reaction rates ? collision and transition state theory, relaxation kinetics, kinetics of photochemical reactions and free radical polymerization, homogeneous catalysis, adsorption isotherms and heterogeneous catalysis.

INORGANIC CHEMISTRY

Main group elements: General characteristics, allotropes, structure and reactions of simple and industrially important compounds: boranes, carboranes, silicones, silicates, boron nitride, borazines and phosphazenes. Hydrides, oxides and oxoacids of pnictogens (N, P), chalcogens (S, Se & Te) and halogens, xenon compounds, pseudo halogens and interhalogen compounds. Shapes of molecules and hard- soft acid base concept. Structure and Bonding (VBT) of B, Al, Si, N, P, S, Cl compounds. Allotropes of carbon: graphite, diamond, C60. Synthesis and reactivity of inorganic polymers of Si and P.

Transition Elements: General characteristics of d and f block elements; coordination chemistry: structure and isomerism, stability, theories of metal- ligand bonding (CFT and LFT), mechanisms of substitution and electron transfer reactions of coordination complexes. Electronic spectra and magnetic properties of transition metal complexes, lanthanides and actinides. Metal carbonyls, metal- metal bonds and metal atom clusters, metallocenes; transition metal complexes with bonds to hydrogen, alkyls, alkenes and arenes; metal carbenes; use of organometallic compounds as catalysts in organic synthesis. Bioinorganic chemistry of Na, K. Mg, Ca, Fe, Co, Zn, Cu and Mo.

Solids: Crystal systems and lattices, miller planes, crystal packing, crystal defects; Bragg?fs Law, ionic crystals, band theory, metals and semiconductors, Different structures of AX, AX2, ABX3 compounds, spinels.

Instrumental methods of analysis: Atomic absorption and emission spectroscopy including ICP-AES, UV- visible spectrophotometry, NMR, mass, Mossbauer spectroscopy (Fe and Sn), ESR spectroscopy, chromatography including GC and HPLC and electro-analytical methods (Coulometry, cyclic voltammetry, polarography . amperometry, and ion selective electrodes).

ORGANIC CHEMISTRY

Stereochemistry: Chirality of organic molecules with or without chiral centres. Specification of configuration in compounds having one or more stereogenic centres. Enantiotopic and diastereotopic atoms, groups and faces. Stereoselective and stereospecific synthesis. Conformational analysis of acyclic and cyclic compounds. Geometrical isomerism. Configurational and conformational effects on reactivity and selectivity/specificity.

Reaction mechanism: Methods of determining reaction mechanisms. Nucleophilic and electrophilic substitutions and additions to multiple bonds. Elimination reactions. Reactive intermediates- carbocations, carbanions, carbenes, nitrenes, arynes, free radicals. Molecular rearrangements involving electron deficient atoms.

Organic synthesis: Synthesis, reactions, mechanisms and selectivity involving the followingalkenes, alkynes, arenes, alcohols, phenols, aldehydes, ketones, carboxylic acids and their derivatives, halides, nitro compounds and amines. Use of compounds of Mg, Li, Cu, B and Si in organic synthesis. Concepts in multistep synthesis- retrosynthetic analysis, disconnections, synthons, synthetic equivalents, reactivity umpolung, selectivity, protection and deprotection of functional groups.

Pericyclic reactions: Electrocyclic, cycloaddition and sigmatropic reactions. Orbital correlation, FMO and PMO treatments.

Photochemistry: Basic principles. Photochemistry of alkenes, carbonyl compounds, and arenes. Photooxidation and photoreduction. Di-??- methane rearrangement, Barton reaction.

Heterocyclic compounds: Structure, preparation, properties and reactions of furan, pyrrole, thiophene, pyridine, indole and their derivatives.

Biomolecules: Structure, properties and reactions of mono- and di-saccharides, physicochemical properties of amino acids, chemical synthesis of peptides, structural features of proteins, nucleic acids, steroids, terpenoids, carotenoids, and alkaloids.

Spectroscopy: Principles and applications of UV-visible, IR, NMR and Mass spectrometry in the determination of structures of organic molecules.

City planning: Evolution of cities; principles of city planning; types of cities & new towns; planning regulations and building byelaws; eco-city concept; sustainable development.

Housing: Concept of housing; neighbourhood concept; site planning principles; housing typology; housing standards; housing infrastructure; housing policies, finance and management; housing programs in India; self help housing.

Landscape Design: Principles of landscape design and site planning; history of landscape styles; landscape elements and materials; plant characteristics & planting design; environmental considerations in landscape planning.

Computer Aided Design: Application of computers in architecture and planning; understanding elements of hardware and software; computer graphics; programming languages ? C and Visual Basic and usage of packages such as AutoCAD, 3D-Studio, 3D Max.

Environmental Studies in Building Science: Components of Ecosystem; ecological principles concerning environment; climate responsive design; energy efficient building design; thermal comfort; solar architecture; principles of lighting and styles for illumination; basic principles of architectural acoustics; environment pollution, their control & abatement.

Visual and Urban Design: Principles of visual composition; proportion, scale, rhythm, symmetry, harmony, datum, balance, form, colour, texture; sense of place and space, division of space; barrier free design; focal point, vista, image ability, visual survey, figure-background relationship.

History of Architecture: Indian ? Indus valley, Vedic, Buddhist, Indo-Aryan, Dravidian and Mughal periods; European ? Egyptian, Greek, Roman, medieval and renaissance periodsconstruction and architectural styles; vernacular and traditional architecture.

Development of Contemporary Architecture: Architectural developments and impacts on society since industrial revolution; influence of modern art on architecture; works of national and international architects; art novuea, eclecticism, international styles, post modernism, deconstruction in architecture.

Building Services: Water supply, sewerage and drainage systems; sanitary fittings and fixtures; plumbing systems, principles of internal & external drainage systems, principles of electrification of buildings, intelligent buildings; elevators & escalators, their standards and uses; airconditioning systems; fire fighting systems, building safety and security systems.

Building Construction and Management: Building construction techniques, methods and details; building systems and prefabrication of building elements; principles of modular coordination; estimation, specification, valuation, professional practice; project management techniques e.g., PERT, CPM etc;

Materials and Structural Systems: Behavioural characteristics of all types of building materials e.g. mud, timber, bamboo, brick, concrete, steel, glass, FRP, different polymers, composites; principles of strength of materials; design of structural elements in wood, steel and RCC; elastic and limit state design; complex structural systems; principles of pre-stressing; tall buildings; principles of disaster resistant structures.

Planning Theory: Regional planning; settlement system planning; history of human settlements; growth of cities & metropolises; principles of Ekistics; rural-urban migration; urban conservation; urban renewal; Five-year plan; structural and sectoral plan.

Techniques of Planning: Planning survey techniques; preparation of urban and regional structure plans, development plans, action plans; site planning principles and design; statistical methods of data analysis; application of G.I.S and remote sensing techniques in urban and regional planning; decision making models.

Traffic and Transportation Planning: Principles of traffic engineering and transportation planning; traffic survey methods; design of roads, intersections, grade separators and parking areas; hierarchy of roads and levels of services; traffic and transport management in urban areas, intelligent transportation system; mass transportation planning; para-transits and other modes of transportation, pedestrian & slow moving traffic planning.

Infrastructure, Services and Amenities: Principles of water supply and sanitation systems; water treatment; solid waste disposal systems; waste treatment, recycle & reuse; urban rainwater harvesting; power supply and communication systems ? network, design & guidelines; demography related standards at various levels of the settlements for health, education, recreation, religious & public-semi public facilities.

Development Administration and Management: Planning laws; development control and zoning regulations; laws relating to land acquisition; development enforcements, urban land ceiling; land management techniques; planning and municipal administration; disaster mitigation management; 73rd & 74th Constitutional amendments; valuation & taxation; revenue resources and fiscal management; public participation and role of NGO & CBO; Institutional networking & capacity building.