Download OU (Osmania University) B.Sc (Bachelor of Science) 2019 Dec 5th Sem (3rd Year) 8170 Chemistry Previous Question Paper
Code No. 8170
FACULTY OF SCIENCE
B.Sc. V-Semester (CBCS) Examination. November! December 2019
Subject : Chemistry
Pa r? V DSC
pe ( ) Max. Marks: 60
Time : 3 Hours
PART ? A (5 x 3 = 15 Marks)
(Short Answer Type)
Note : Answer any five of the following questions.
?'1?
Cupric sulphate is blue on heating strongly it become colourless why? ?_Explaln.
What are boranes and carboranes? Give one example?each.
What is Carbyl Amine reaction? Write its use; 5..?
How do you prepare diazonium salt? Write its equation, ?
What is half life period? A ?rst order reaction is found to have rate constant
K of 7.39 x 10'5 sec". Calculate the half life period of the reagion.
What are consecutive reactions? Give one examyezf
Explain about batho chromic and hypso chromio shifte/ v ,-
De?ne phosphorescence and ?uorescence..5Exblein with diagram.
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mVO)
W 3% 9,.
PART 4mM?a?rks)
(Essay Mayer Type)
Note: A"$W{' ALL from the questions.
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9 (3) Explain diagrammatica?rEQIiQipE) pattern of d-orbitols in square planar
complexes by taking?or?i?e ?X?mpIe. (11)
j ?K. ?J? ()Fz
(b) Explain the deter .gnatioh of magnetism moment (p) of magnetic by Gouy's
method Experimentally??
10 (a) Explaim 'th ni?echanism of following reactions. (11)
(I) ngr?eingyon (ii) Nitration of Aromatic Amines
_ .f | ' 0R
(b) m? e electrophilic substitution reactions of Furan, thiophene and pyrrole. /
11 .Vh'??t?is a rate of reaction? Explain the factors in?uencing rate of reaction (11)
OR I
(b) How do you determine order of reaction by Ostwald's isolation methods
12 (a) Expiain the following photo chemical laws. ?/
(g) Grothus ~ Draper law (12)
(II) Stark Einstein?s law of photochemical equivalence
' 0R
(b) Explain the modes of vibrati '
ons In 0! atomac m I '
H20 and CO; molecules as an exafnpt. 0 ecules by takmg
tit?i
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