THERMODYNAMICS
Notation used:
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P-pressure, V-volume, T-temperature, S-entropy, H-enthalpy, U-internal energy, Cp, Cv – specific heats.
Specific properties are designated by lower case symbols.
Subscript 'f' refers to saturated liquid and subscript 'g' refers to saturated vapor.
Universal gas constant = 8.314 kJ/kmol K
Molecular mass of air in kg/kmol = 29
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Specific heat ratio of air (?air) = 1.4
Q. 1 – Q. 9 carry one mark each.
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A gas expands following the relation PVn = constant, from the initial state P1, V1 to final volume V2 = 2V1. For the values of 'n' mentioned below, maximum displacement work is obtained for
- n = - 1
- n = 0
- n=1
- n = 1.4
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A 100 O electrical resistor is heated steadily by passing a current of 20 A. If heating is performed in the ambient at 30°C, the rate of increase in entropy of the universe in kW/K is
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As per Clausius inequality, a system operating on an irreversible cycle transfers
- more entropy to the sink than what it receives from the source
- as much entropy to the sink as it receives from the source
- less entropy to the sink than what it receives from the source
- less entropy to the sink than that corresponding to a reversible cycle
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The critical point of a substance corresponds to the state
- at which the solid, liquid and vapor phases are in equilibrium
- beyond which liquid will require very large amount of heat to become vapor
- beyond which solid sublimates directly to the vapor state
- beyond which the distinction between liquid and vapor phases disappears
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Consider the process of sensible cooling of air with 60% relative humidity at constant pressure. Which one of the following statements is TRUE for this process?
- Both humidity ratio and relative humidity increase during the process.
- The humidity ratio decreases continuously due to condensation.
- The dry bulb temperature decreases but the wet bulb temperature increases.
- The humidity ratio remains constant.
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The coefficient of performance (COP) of a reversible refrigerator operating between two thermal reservoirs is 4.0. The efficiency (in percentage) of a reversible heat engine operating between the same temperature limits is
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Differential change in specific enthalpy of a superheated vapor for which ideal gas approximation does not hold, is given by the expression
- dh = Cp dT
- dh = Cp dT + (?h/?v)T dv
- dh = Cp dT + (?h/?p)T dp
- dh = Cp dT + (?h/?p)T dp
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An ideal gas mixture of oxygen (molecular weight = 32 kg/kmol) and carbon dioxide (molecular weight = 44 kg/kmol) has a mass composition of 40% and 60% respectively. If the total pressure is 200 kPa, the partial pressure of oxygen (in kPa) is
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In an ideal Rankine cycle, increase in superheat of vapor at the exit of boiler leads to
- decrease in net work output from the cycle
- increase in cycle efficiency
- decrease in cycle efficiency
- decrease in quality of steam at the exit of the turbine
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Q. 10 – Q. 22 carry two marks each.
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Two moles of air at 1 atm, 21.1°C goes through an adiabatic device and separates into a hot stream of 0.4 moles at 1 atm, 176.3°C and a cold stream of 1.6 moles at 1 atm, –17.7°C, without any external work. It can be concluded that
- the total entropy change is zero
- the total entropy change for the process is positive
- the device violates Second Law of Thermodynamics
- the device violates First Law of Thermodynamics
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For a real gas undergoing volume expansion through a porous plug with a = (1/Cp)(?v/?T)p, the Joule- Thomson cooling effect is observed if
- 0<aT<1
- aT = 1
- aT > 1
- aT = 0
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A lead bullet at 100°C traveling at 500 m/s, strikes a target and adiabatically comes to rest. If the specific heat of lead is 92 J/kg °C, melting temperature is 327.5 °C and heat of fusion is 108 kJ/kg, the percentage mass of lead in the bullet that is melted by collision is
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An air-water vapor mixture with volume 100 m³ at 100 kPa, 35°C is at 75 % relative humidity. Taking saturation pressure of vapor at 35°C as 5.63 kPa, the mass of vapor in the mixture in kg is
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An ideal gas of 1 kg mass enclosed inside a rigid vessel at the initial temperature 1200 K is employed as a heat source. The specific heat Cv of the gas is 718 J/kg K. The maximum work in kJ that can be developed by operating a heat engine between the ideal gas and the ambient at 300 K is
- 646.2
- 484.7
- 387.7
- 347.6
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The boiling point of water changes from 99.62°C to 105.99°C when the system pressure is changed from 1 bar to 1.25 bar. The boiling point value (in °C) corresponding to a pressure of 1.5 bar is
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An ideal gas expands in an adiabatic frictionless nozzle from the inlet conditions of 31 bar, 800 K to the ambient pressure of 1 bar at the outlet. The specific heat Cp for the gas is 1 kJ/kg K and the specific heat ratio ? = 1.4. Neglecting inlet kinetic energy, the velocity of the gas (in m/s) at the nozzle exit is
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- 32
- 500
- 707
- 1000
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One kmol of hydrogen (molecular weight = 2 kg/kmol, specific heat ratio ? = 1.4) at 1 bar, 300 K mixes with one kmol of nitrogen (molecular weight = 28 kg/kmol, specific heat ratio ? = 1.4) at 1 bar, 300 K in an adiabatic vessel. The final mixture is also at 1 bar, 300 K. The entropy change (in kJ/K) for the process is
- -5.76
- zero
- 5.76
- 11.53
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A cycle 1-2-3-1 is proposed with the following processes:
1-2: Constant pressure expansion, 2-3: Reversible adiabatic expansion, 3-1: Irreversible adiabatic compression. Which one of the following statements is TRUE?
- The net work of the cycle is zero because there is no heat transfer.
- The cycle is feasible and can deliver net positive work.
- The cycle is impossible according to Kelvin-Planck statement.
- The cycle is impossible in accordance with First Law of Thermodynamics.
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One kg of saturated liquid-vapor mixture of water at 150 kPa (uf = 467 kJ/kg, vf = 0.001053 m³/kg; ug = 2520 kJ/kg and vg = 1.159 m³/kg) with quality of 0.7 is enclosed in a piston cylinder assembly. Heat is added at constant pressure to this system while a paddle wheel transfers a work of 50 kJ. The mixture eventually attains saturated vapor state. The amount of heat added to the mixture (in kJ) is
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Air enters a pipe at 1 bar and flows isothermally at the rate of 1 kg/s. Due to pipe friction, the pressure drop between two sections of the pipe is 7% of the pressure at inlet section. For ambient temperature, To = 300 K, the rate of irreversibility (in W) between the two sections is
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A pump raises pressure of saturated liquid water at 100 kPa (density ? = 959 kg/m³) to 2 MPa. The isentropic efficiency of the pump is 0.92. The work done by the pump (in J/kg) is
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In a Brayton cycle with with air (? = 1.4) as working fluid, Tmin = 300 K and Tmax = 1000 ?. The pressure ratio corresponding to maximum net work per cycle is
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END OF THE QUESTION PAPER
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