Roll No. [T TTTTTT] [ ] Total No. of Pages : 02
Total No. of Questions : 11
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B.Sc. (Honours) Chemistry (Sem.-1)
ORGANIC CHEMISTRY-I
Subject Code : BHCL-102-19
M.Code : 77224
Time : 3 Hrs. Max. Marks : 60
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INSTRUCTIONS TO CANDIDATES :
- SECTION-A is COMPULSORY consisting of EIGHT questions carrying TWO marks each.
- SECTION-B contains EIGHT questions carrying FOUR marks each and students have to attempt any SIX questions.
- SECTION-C will comprise of two compulsory questions with internal choice in both these questions. Each question carries TEN marks.
SECTION-A
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- Write briefly :
- What is the optical activity?
- What are localized and de-localized chemical bonds?
- What is aromaticity?
- Explain the third law of thermodynamics.
- What are geometrical isomers?
- What is Markownikoff’s rule?
- Explain the boat and chair form in cyclohexane.
- Explain the Saytzeff rule.
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SECTION-B
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- Explain the Clatherates with examples.
- Explain the reactivity order of carbocation and factors affect this order.
- What are enantiomers and properties of enantiomers?
- Explain Threo and Erythro isomer form.
- Explain the D and L system with examples.
- Explain the Bayer’s strain theory.
- Explain the 1,2-addition in dienes.
- Explain the synthesis of DDT.
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SECTION-C
- Explain the Hydroboration-oxidation of alkenes.
OR
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Explain Diel’s Alder reaction with suitable example. - What do you understand by SN1 and SN2 mechanism? Illustrate your answer by considering the hydrolysis of alkyl halides.
OR
Explain the Birch Reduction with example.
NOTE : Disclosure of Identity by writing Mobile No. or Making of passing request on any page of Answer Sheet will lead to UMC against the Student.
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