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Code: 15A51103
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B.Tech I Year I Semester (R15) Supplementary Examinations November/December 2019
Time: 3 hours Max. Marks: 70
BASIC CHEMISTRY
(Food Technology)
PART - A
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(Compulsory Question)Answer the following: (10 X 02 = 20 Marks)
- What is meant by entropy?
- What is meant by redox reaction?
- What is meant by order of reaction?
- What does valency bond theory explain?
- What are the important components in terms of instrumentation of Microwave spectroscopy?
- What is meant by IR spectroscopy? Give its important applications.
- What is meant by polymerization?
- What is meant by Friedel Craft Alkylation?
- Define the degree of freedom.
- What are important properties of colloids?
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PART - B
(Answer all five units, 5 X 10 = 50 Marks)
UNIT - I
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- (a) What do you understand by thermodynamic system and surroundings?
(b) Describe the important applications of emf measurements.OR
- (a) Give an account of electrochemical series and its applications.
(b) Explain about electrochemical cells.
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UNIT - II
- (a) What do you understand by the term rate-determining steep of a complex reaction? What is steady-state hypothesis?
(b) What are bonding and antibonding molecular orbitals?OR
- (a) Write short notes on parallel reaction
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(b) Draw molecular orbital diagram for NO molecule.
UNIT - III
- (a) Which selection rule is used in Infrared spectroscopy? Explain about finger print region.
(b) Explain why [Ni(CO)4] is tetrahedral, [Ni(H2O)6]2+ is square planar and [Ni(NH3)6]2+ is octahedral using valence bond theory.OR
- (a) Briefly explain the Beer-Lambert's law and give its applications.
(b) Brief account on Haemoglobin with respect to metal ion.
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UNIT - IV
- (a) Write short notes on Perkin's reaction.
(b) Illustrate the details of Papaverine.OR
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- (a) Write short notes on Toxol.
(b) What are Biomolecules? Explain aminoacids.
UNIT - V
- (a) State and Explain the phase role.
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(b) Explain basic principle of TLC and what are its usefulness?OR
- (a) Draw and explain the phase diagram of water system, i.e. one-component system.
(b) What are different separation techniques like crystallization.
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