Master (CRCH) Examination, November / December 2019
Subject : Chemistry
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Time : 3 Hours
Paper - I
Max. Marks: 80
PART - A (1l x 4 = 32 Marks)
(Short Answer Type)
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Note: Answer any EIGHT of the following questions.
- Explain Fajan's rule with examples
- Explain the structure of Diborane
- Write the differences between Bonding and Anti-Bonding Molecular Orbitals (BMOs and ABMOs)
- What is Inductive effect?
- Explain Markonikoff's rule with mechanism
- Write a short note on Diels - Alder reaction with example
- Derive and explain de-Broglie's wave theorem
- Why gases deviates from ideal behaviour ? Explain
- Write about Raoults law
- Explain common ion effect with example
- Write the differences between enantiomers and diastereomers
- What is sodium carbonate extract?
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PART - B (4 x 12 = 48 Marks)
(Essay Answer Type)
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Note: Answer ALL from the questions.
- (a) Draw MOED of NO. Explain the magnetic character and Bond order
OR
(b) What are silicones? Explain the different types of silicones. - (a) What is Mesomeric effect? Explain the acidity of Phenol.
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OR
(b) Explain Friedel-Crafts Alkylation and Acylation with mechanism and examples. - (a) Define surface tension and explain its determination by Stalagmometer.
OR
(b) Explain Joul-Thompson effect and liquification of gases by Linde's process. - (a) Explain Bayer-strain theory (BST).
OR
(b) Derive Bragg's equation.
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