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Firstranke DURhD in Chemistry.
Topic:- CHEM PHD S2
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Parameter defining microcanonical, canonical and grand canonical ensembles are: [Question ID = 10022]
- (N, V, T), (N, V, E) and (μ, V, Τ) [Option ID = 40082]
- (N, V, E), (N, V, T) and (μ, V, Τ) [Option ID = 40083]
- (Ν, V, Τ), (μ, V, T) and (N, V, E) [Option ID = 40084]
- (μ, V, Τ), (N, V, T) and (N, V, E) [Option ID = 40085]
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Correct Answer :- • (N, V, E), (N, V, T) and (μ, V, Τ) [Option ID = 40083]
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What is Scifinder ? [Question ID = 10023]
- World's largest database of chemistry literature [Option ID = 40086]
- Country's largest database of chemistry literature [Option ID = 40087]
- Continental's largest database of chemistry literature [Option ID = 40088]
- India's largest database of chemistry literature [Option ID = 40089]
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Correct Answer :- • World's largest database of chemistry literature [Option ID = 40086]
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Match the shape to the formula. Which pairing is incorrect? [Question ID = 10024]
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- [XeF5]; pentagonal planar [Option ID = 40090]
- XeO3; trigonal planar [Option ID = 40091]
- XeF4; square planar [Option ID = 40092]
- [XeF3]+; T-shaped [Option ID = 40093]
Correct Answer :- • XeO3; trigonal planar [Option ID = 40091]
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Langmuir adsorption isotherm equation shows the variation of extent of adsorption as a function of: [Question ID = 10026]
- Pressure [Option ID = 40098]
- Temperature [Option ID = 40099]
- pH of medium [Option ID = 40100]
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Correct Answer :- • Pressure [Option ID = 40098]
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Which statement is incorrect about XeF2, XeF4 and XeF6? [Question ID = 10027]
- All three compounds react with silica glass at 298 K. [Option ID = 40102]
- All three compounds can be sublimed under vacuum. [Option ID = 40103]
- All three compounds are oxidizing agents. [Option ID = 40104]
- All three compounds react with H2O. [Option ID = 40105]
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Correct Answer :- • All three compounds react with silica glass at 298 K. [Option ID = 40102]
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Green chemistry aims to? [Question ID = 10029]
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- Design chemical products and process that maximize profits [Option ID = 40110]
- Design safer chemical products and processes that reduce or eliminate the use and generation of hazardous substances [Option ID = 40111]
- Design chemical products and processes that work most efficiently [Option ID = 40112]
- Utilize non-renewable energy [Option ID = 40113]
Correct Answer :- • Design safer chemical products and processes that reduce or eliminate the use and generation of hazardous substances [Option ID = 40111]
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An aqueous solution containing a concentration of 2.5 x 10-8 OH- ions will have a pH of which of the following? [Question ID = 10030]
- 6.40 [Option ID = 40114]
- 6.42 [Option ID = 40115]
- 7.40 [Option ID = 40116]
- 7.76 [Option ID = 40117]
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Correct Answer :- • 6.40 [Option ID = 40114]
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An appropriate source to find out descriptive information is [Question ID = 10031]
- Bibliography [Option ID = 40118]
- Directory [Option ID = 40119]
- Encyclopedia [Option ID = 40120]
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Correct Answer :- • Encyclopedia [Option ID = 40120]
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Which of the following statements regarding a conjugated system is false? [Question ID = 10032]
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- Electrons are shared between more than two atoms, rather than being localized within bond joining two specific atoms [Option ID = 40122]
- The molecule must be cyclic (ring-structured) [Option ID = 40123]
- The molecule must feature alternating single and double bonds [Option ID = 40124]
- The system arises from the overlap of neighboring p-orbital [Option ID = 40125]
Correct Answer :- • The molecule must be cyclic (ring-structured) [Option ID = 40123]
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The standard reduction potential Eº for half reactions are : Zn = Zn2+ + Ze E° = +0.76 V Fe = Fe2+ + Ze E° = + 0.41 V The EMF of the cell reaction Fe2+ + Zn = Zn2+ + Fe is : [Question ID = 10034]
- +0.41 V [Option ID = 40130]
- +0.76 V [Option ID = 40131]
- +0.35 V [Option ID = 40132]
- +1.17 V [Option ID = 40133]
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Correct Answer :- • +0.76 V [Option ID = 40131]
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The main purpose of research in education is to [Question ID = 10035]
- Increase social status of an individual [Option ID = 40134]
- Increase job prospects of an individual [Option ID = 40135]
- Help in the personal growth of an individual [Option ID = 40136]
- Help the candidate become an eminent educationist [Option ID = 40137]
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Correct Answer :- • Help the candidate become an eminent educationist [Option ID = 40137]
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Spectroscopic transitions leading to the change in polarizibility ellipsoid of a molecule will appear at which region of the electromagnetic spectrum? [Question ID = 10036]
- Microwave [Option ID = 40138]
- Rotational [Option ID = 40139]
- Infra-red [Option ID = 40140]
- Raman [Option ID = 40141]
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Correct Answer :- • Raman [Option ID = 40141]
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What is the unit of cell constant of a conductor? [Question ID = 10038]
- cm-1 [Option ID = 40146]
- cm [Option ID = 40147]
- Siemens [Option ID = 40148]
- None of these [Option ID = 40149]
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Correct Answer :- • cm-1 [Option ID = 40146]
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In the process of conducting research 'Formulation of Hypothesis is followed by: [Question ID = 10039]
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- Statement of Objectives [Option ID = 40150]
- Analysis of Data [Option ID = 40151]
- Selection of Research Tools [Option ID = 40152]
- Collection of Data [Option ID = 40153]
Correct Answer :- • Selection of Research Tools [Option ID = 40152]
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A 10 cm³ of NaOH solution of pH 8 is mixed with 990 cm³ of water. What is the pH of the resulting solution? [Question ID = 10040]
- 8 [Option ID = 40154]
- 7 [Option ID = 40155]
- 6 [Option ID = 40156]
- Between 7 and 8 [Option ID = 40157]
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Correct Answer :- • Between 7 and 8 [Option ID = 40157]
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The heterocyclic ring present in the amino acid histidine is: [Question ID = 10041]
- pyridine [Option ID = 40158]
- pyrrole [Option ID = 40159]
- indole [Option ID = 40160]
- imidazole [Option ID = 40161]
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Correct Answer :- • imidazole [Option ID = 40161]
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The essential qualities of a researcher are: [Question ID = 10042]
- Spirit of free enquiry [Option ID = 40162]
- Reliance on observation and evidence [Option ID = 40163]
- Systematization or theorizing of knowledge [Option ID = 40164]
- All of these [Option ID = 40165]
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Correct Answer :- • All of these [Option ID = 40165]
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The second-order rate constant (k2) for the reaction of I- with trans-[PtCl(CH3) (PEt3)2] in methanol at 30°C is 40 L.mol-1s-1 and with N³- is 7.0 L.mol-1s-¹. The given "Pt values are 5.42 and 3.58 for the two nucleophiles respectively. The value of nucleophilic discrimination constant (S) and the first-order rate constant (C) for the reaction could be: [Question ID = 10043]
- 0.41, -0.61 [Option ID = 40166]
- 0.41, -0.41 [Option ID = 40167]
- 0.61, -0.41 [Option ID = 40168]
- None of these [Option ID = 40169]
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Correct Answer :- • 0.41, -0.61 [Option ID = 40166]
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The ratio of the relative intensities of the carbon signals in the first order 13C NMR spectrum of CD3Cl is: [Question ID = 10044]
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- 1:4:6:4:1 [Option ID = 40170]
- 1:3:3:1 [Option ID = 40171]
- 1:6:15:20:15:6:1 [Option ID = 40172]
- 1:3:6:7:6:3:1 [Option ID = 40173]
Correct Answer :- 1:3:6:7:6:3:1 [Option ID = 40173]
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Research means [Question ID = 10045]
- Searching again and again [Option ID = 40174]
- Finding solution to any problem [Option ID = 40175]
- Working in a scientific way to search for truth of any problem [Option ID = 40176]
- None of these [Option ID = 40177]
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Correct Answer :- • Working in a scientific way to search for truth of any problem [Option ID = 40176]
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What is the final, stable nuclide, X, if radon-222 decays by the emission of four alpha particles and four beta particles? [Question ID = 10046]
- tungsten-206 [Option ID = 40178]
- tungsten-214 [Option ID = 40179]
- platinum-210 [Option ID = 40180]
- lead-206 [Option ID = 40181]
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Correct Answer :- • lead-206 [Option ID = 40181]
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Which type of study is loosely structured and designed to expand understanding of a topic and provide insights? [Question ID = 10048]
- Formal [Option ID = 40186]
- Descriptive [Option ID = 40187]
- Exploratory [Option ID = 40188]
- Experimental [Option ID = 40189]
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Correct Answer :- • Exploratory [Option ID = 40188]
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In which region of the infrared spectrum would you expect to find a peak characteristic of a triple bond stretch? [Question ID = 10049]
- 4000 3000 cm-1 [Option ID = 40190]
- 2500-2000 cm-1 [Option ID = 40191]
- 2000-1500 cm-1 [Option ID = 40192]
- 1500-750 cm-1 [Option ID = 40193]
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Correct Answer :- • 2500-2000 cm-1 [Option ID = 40191]
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For Cr(CO)6, which of the following statements is correct? [Question ID = 10050]
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- 4 Cr-O bonds are equivalent [Option ID = 40194]
- 6 Cr-O bonds are equivalent [Option ID = 40195]
- All Cr-O bonds are equivalent [Option ID = 40196]
- All Cr-O bonds are nonequivalent [Option ID = 40197]
Correct Answer :- • 6 Cr-O bonds are equivalent [Option ID = 40195]
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Which of the following is a Wiley Journal? [Question ID = 10051]
- Chemical Communication [Option ID = 40198]
- Organic Letter [Option ID = 40199]
- Angewandte Chemie [Option ID = 40200]
- Organic & Biomolecular Chemistry [Option ID = 40201]
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Correct Answer :- • Angewandte Chemie [Option ID = 40200]
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The term symbol/s for S = 1/2 and I = 2 are: [Question ID = 10052]
- 3P2, 3P₁ and 3Po [Option ID = 40202]
- 2P5/2 and 2P3/2 [Option ID = 40203]
- 2D5/2 and 2D3/2 [Option ID = 40204]
- 2D3 and 2D4 [Option ID = 40205]
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Correct Answer :- • 2D5/2 and 2D3/2 [Option ID = 40204]
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The frequency of 3 x 1018 Hz falls in the: [Question ID = 10053]
- Microwave region [Option ID = 40206]
- Infra-red region [Option ID = 40207]
- Visible and ultraviolet region [Option ID = 40208]
- X-ray region [Option ID = 40209]
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Correct Answer :- • X-ray region [Option ID = 40209]
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Powder X-ray diffraction practice gives the first (lowest) diffraction angle as 15.5° in an experiment with monochromatic X-rays of wavelength 0.154 nm. The corresponding cell length responsible for this diffracted beam is which of the following? [Question ID = 10054]
- 0.29 nm [Option ID = 40210]
- 29 nm [Option ID = 40211]
- 0.15 nm [Option ID = 40212]
- 2.3 nm [Option ID = 40213]
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Correct Answer :- • 0.29 nm [Option ID = 40210]
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Which statement about the trans-effect and the trans-influence is correct? [Question ID = 10056]
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- The trans-influence is a ground-state effect, whereas the trans-effect has a kinetic origin [Option ID = 40218]
- The trans-effect is a ground-state effect, whereas the trans-influence has a kinetic origin [Option ID = 40219]
- Both the trans-effect and trans-influence are ground-state effects [Option ID = 40220]
- Rates of substitution are affected by the trans-effect but have nothing to do with the trans-influence of ligands. [Option ID = 40221]
Correct Answer :- • The trans-influence is a ground-state effect, whereas the trans-effect has a kinetic origin [Option ID = 40218]
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Which of the following is not a journal? [Question ID = 10057]
- Science [Option ID = 40222]
- Tetrahedron Letters [Option ID = 40223]
- Sci-finder [Option ID = 40224]
- Nature [Option ID = 40225]
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Correct Answer :- • Sci-finder [Option ID = 40224]
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Electronic transitions originating from the 25 energy level of an atom to higher levels belong to which series? [Question ID = 10059]
- Lyman Series [Option ID = 40230]
- Balmer Series [Option ID = 40231]
- Brackett Series [Option ID = 40232]
- Pfund Series [Option ID = 40233]
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Correct Answer :- • Balmer Series [Option ID = 40231]
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Cryogenic liquids are: [Question ID = 10060]
- Materials with boiling points of less than -73°C [Option ID = 40234]
- Materials with boiling points of more than 73°C [Option ID = 40235]
- Materials with boiling points 100°C [Option ID = 40236]
- Materials which are toxic and colored [Option ID = 40237]
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Correct Answer :- • Materials with boiling points of less than -73°C [Option ID = 40234]
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It takes 12 minutes for the concentration of a radioactive species to decay to its 1/8th value of its original concentration. What is the rate constant of this radioactive decay reaction? [Question ID = 10061]
- 240 s-1 [Option ID = 40238]
- 0.00231 s-1 [Option ID = 40239]
- 0.00289 s-1 [Option ID = 40240]
- 865.8 s-1 [Option ID = 40241]
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Correct Answer :- • 0.00289 s-1 [Option ID = 40240]
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The ground state of a harmonic oscillator has number of nodes: [Question ID = 10062]
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- 3 [Option ID = 40242]
- 2 [Option ID = 40243]
- 1 [Option ID = 40244]
- 0 [Option ID = 40245]
Correct Answer :- • 0 [Option ID = 40245]
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As the temperature of a solution is increased, the conductance in an electrolyte solution will [Question ID = 10065]
- Become zero [Option ID = 40254]
- Remain the same [Option ID = 40255]
- Increase [Option ID = 40256]
- Decrease [Option ID = 40257]
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Correct Answer :- • Increase [Option ID = 40256]
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In a reverse micro-emulsion, Wo is defined as: [Question ID = 10066]
- Wo = [surfactant] / [water] [Option ID = 40258]
- Wo = [water] / [surfactant] [Option ID = 40259]
- Wo = 1/ [water] [Option ID = 40260]
- Wo = 1/ [surfactant] [Option ID = 40261]
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Correct Answer :- • Wo = 1/ [surfactant] [Option ID = 40261]
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In an inner-sphere electron transfer reaction, which of the following ligands could not act as a bridging ligand? [Question ID = 10067]
- 1,10-phenanthroline [Option ID = 40262]
- 4,4'-bipyridine [Option ID = 40263]
- Pyrazine [Option ID = 40264]
- bis(4-pyridyl)methane [Option ID = 40265]
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Correct Answer :- • 1,10-phenanthroline [Option ID = 40262]
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A doctor studies the relative effectiveness of two drugs of dengue fever. His research would be classified as: [Question ID = 10068]
- Descriptive Survey [Option ID = 40266]
- Experimental Research [Option ID = 40267]
- Case Study [Option ID = 40268]
- Ethnograph [Option ID = 40269]
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Correct Answer :- • Experimental Research [Option ID = 40267]
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Which one among the following journal has the highest impact? [Question ID = 10070]
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- Science [Option ID = 40274]
- Organic Letters [Option ID = 40275]
- Angewandte Chemie [Option ID = 40276]
- Nature [Option ID = 40277]
Correct Answer :- • Science [Option ID = 40274]
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Which of the following does not used to calculate h-index? [Question ID = 10071]
- Web of Science [Option ID = 40278]
- Scopus [Option ID = 40279]
- Google Scholar [Option ID = 40280]
- Sci-finder [Option ID = 40281]
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Correct Answer :- • Sci-finder [Option ID = 40281]
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Amongst the following reaction, the major products formed in the following photochemical reactions are:
This download link is referred from the post: DUET Last 10 Years 2011-2021 Question Papers With Answer Key || Delhi University Entrance Test conducted by the NTA
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